As the title says there is an easy way to have all missions unlocked from the start, follow these easy steps and get all from beginning.

1.- Simply go to:
%USERPROFILE%\Documents\My Games\Starship Troopers\PlayerData

And find the "Unlocks" file.

2.- Open with notepad

3.- Copy & Paste the following list into the file:
Kwalasha_Foothold
Kwalasha_Hole_Patrol
Kwalasha_Peace_of_Mine
Kwalasha_Cave_Cleaning
Kwalasha_Prison
Kwalasha_Power_Struggle
Kwalasha_Human_Mine
Kwalasha_Tide_Breaker
Kwalasha_Burning_Skies
Kwalasha_Canyon
Kwalasha_Silent_Night
Kwalasha_Razor_Run
Kwalasha_Guardians
Kwalasha_Federatsiyagrad
Kwalasha_Sewers
Kwalasha_Perimeter
Kwalasha_Airfield
Kwalasha_Gatekeeper
Kwalasha_Guillotine
Lava_Lead_By_Sample
Lava_Trophy_Hunt
Lava_Dragon_Island
Lava_Blazing_Trail
Lava_Central_Access
Lava_Flash_Point
Metropolis_Railway
Metropolis_Retreat
Metropolis_Bridges
Metropolis_Rooftops
Metropolis_Police_Station
Metropolis_Starport
Metropolis_City
Metropolis_Brain_Lair

Your file should look like this:

3.- Click on file and save it


4.- That´s it!, Enjoy full missions even DLCs.