Love the pose and expression in this poster. The angle from the subject is great too. The only thing is that the warm lighting is too intense and the rim lighting from the left is too subtle. I can see that you're going for more of a sunset look, but the intensity is more fit for a blazing house fire off camera. I would turn down the light and volumetric intensities down a notch or two and move the light source a little more down as if it's coming from the horizon. In your photo editor of choice, I also recommend to bring out more of those blues in the sky and Scout's cosmetics to further balance and diversify the colors in this poster (since blue is opposite of orange). Bring up the back light's intensity while you're adjusting the orange light to help further separate the subject from the background. Hope you found this helpful!